Study on Preparation and Performance of High Swelling Bentonite

Resumo

For improving the expansibility of natural Ca-based bentonite (Ca-Bent), the Ca-Bent was modified with
sodium dodecyl benzene sulfonate(SDBS)-Na2CO3 complex agent by microwave semi-dry method. And the
ratio of Na2CO3 to SDBS, microwave power, radiation time and initial temperature on the modification were
studied. Furthermore, X-ray diffraction (XRD) patterns and infra-red spectrum (IR) were carried out to
characterize , which obtain microstructure of samples. The result showed that the optimized experimental
parameters are obtained as follows: Na2CO3 to SDBS ratio 1:1, radiation time 2min, microwave power 600W
and initial temperature 120K. Besides, under the optimization conditions, the modified bentonite has swelling
volume of 68.5mL/g, cation exchange capacity of 56.2mmol/102g and yield point and plastic viscosity ratio
of 1.67, respectively. A comparison of the single factor experiment and orthogonal experiment indicates that
the SDBS and Na2CO3 have synergistic effect in the process of modification, especially, under the optimum
microwave condition, Na2CO3 increased the anion activity of SDBS, which enhanced the hydrophilicity of
modified bentonite. The experimental result show that the process improves the swelling volume of bentonite
and the comprehensive performance. So, the modified bentonite was a perfect additive in water drilling mud.
Keywords: Ca-Bent, SDBS-Na2CO3 complex agent, high swelling.