Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries

Autores

  • Hirankumar Gurusamy Department of Physics, Ramakrishna Mission Vivekananda College, Chennai
  • Sakunthala Ayyasamy Solid State Ionics Lab, Department of Applied Physics, Karunya Institute of Technology and Sciences, Coimbatore 641 114, Tamil Nadu, India https://orcid.org/0000-0002-9945-6272
  • Daries Bella Department of Physics, Stella Maris College, Chennai 600 086, Tamil Nadu, India https://orcid.org/0000-0003-3207-5712

Palavras-chave:

electrolyte, lithium ionic conductivity, electrochemical properties, impedance spectroscopy

Resumo

The non-aqueous electrolyte system comprising of the lithium nonafluoro-1-butane sulfonate (LiNfO) as a potential lithium ion-conducting salt in an equivalent binary mixture of propylene carbonate (PC) and 1, 2-dimethoxyethane (DME) as the solvent was explored for the lithium battery applications. The LiNfO based non-aqueous liquid electrolyte (NALE) system showed the highest ionic conductivity of 2.66 x 10-3 S cm-1 at ambient temperature, and a potential window stability of ~5 V. The lithium ion cells, Li/NALE//LiCoO2 werefabricated with the proposed non-aqueous electrolyte. The cell with particular composition of electrolyte delivered a high specific discharge capacity of 154 mA h g-1 at ambient temperature. The potential advantages of the proposed NALE are discussed in detail.

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Publicado

2022-02-25

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v. 26 n. 4 (2021): Pré-Publicação

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Materials and Energy

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